Mitochondrial DNA and relationship between ogranisms?

After reading Bryan Sykes' book, "The Seven Daughters of Eve", I came across a chapter which disucssed Mitochondrial DNA and how it is used to link back ancestory of organisms. I do understand this concept where the mitochondrial DNA is inherited from the mother and therefore is constant unless it undergoes mutions over the generations, but what I would like to understand is how Mitochondrial DNA can be used to determine relationships between organisms..

Thanks for the help!

can DNA analysis be used to classify organisms into baramins?
why/not.

Please list interesting organisms that have been modified using recombinant DNA technology - excluding GloFish. Thanks!